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HCnN, n = 5,7,9
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Nitrogen |
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Nuclear
Quadrupole Coupling Constants |
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in Cyanopolyynes |
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Table 1. 14N nqcc's in HC5N, HC7N, HC9N (MHz). |
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Calc. |
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Expt / Ref |
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HC5N |
Xzz |
-
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4.348 |
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4.242(30) [1] |
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HC7N |
Xzz |
- |
4.343 |
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4.29(16) [2] |
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HC9N |
Xzz |
- |
4.345 |
- |
4.84(21) [2] |
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| Table 2. CN Bond lengths ... |
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CN (Å) |
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HC5N |
1.161 |
rs [1] |
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HC7N |
1.1611 |
ro [2] |
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HC9N |
1.161 |
ro [2] |
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[1] G.Winnewisser, R.A.Creswell, and
M.Winnewisser, Z.Naturforsch. 33a,1169(1978). |
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[2] M.C.McCarthy, E.S.Levine, A.J.Apponi,
and P.Thaddeus, J.Mol. Spectrosc. 203,75(2000). |
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See also ... |
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L.Bizzocchi, C.DelgiEsposti, and P.Botschwina,
J.Mol.Spectrosc. 225,145(2004). ro, rs, rm(1),
and re, molecular structures for HC5N. |
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HCN |
HCCCN |
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Table of Contents |
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Molecules/Nitrogen |
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HCnN.html |
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Last
Modified 22 May 2003 |
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